[40] Roel L. M. Bienenmann, Anne Olarte Loyo, Martin Lutz, Daniël L. J. Broere* 
Mechanistic Investigation Into Copper(I) Hydride Catalyzed Formic Acid Dehydrogenation
Chemrxiv 2024 ​DOI: 10.26434/chemrxiv-2024-cg4fk
First published on ChemRxiv on Feb 14th 2023

Broere Group

[40] Roel L. M. Bienenmann, Marianne R. de Vries, Martin Lutz, Daniël L. J. Broere* 
Understanding the Remarkable Stability of Well-defined Dinuclear Copper(I) Carbene Complexes
Chemrxiv 2024 DOI: 10.26434/chemrxiv-2024-gz9hl
First published on ChemRxiv on Jan 19th 2023

Broere Group

[39] Errikos Kounalis, Dylan van Tongeren, Stanislav Melnikov, Martin Lutz, Daniël L. J. Broere* 
Pendulum-like Hemilability in a Ti-based Frustrated Lewis Trio
Chemical Science 2024, 15, 55555563
First published on ChemRxiv on Nov 6th 2023

Broere Group

[38] Phebe H. Langevelde,# Errikos, Kounalis,# Lars Killian,Emily Monkcom, Daniël L. J. Broere,* Dennis G. H. Hetterscheid*
Mechanistic Investigations into the Selective Reduction of Oxygen by a MCO T3 site-inspired Copper Complex
ACS Catalysis 2023, 3, 5712–5722
# Equal contribution — First published on ChemRxiv on Oct 20th 2022

Broere Group

[37] Lars Killian,#  Roel Bienenmann,# Daniël L. J. Broere*
Quantification of the Steric Properties of 1,8-Naphthyridine Based Ligands in Dinuclear Complexes
Organometallics 2023, 42, 27–37
# Equal contribution   First published on ChemRxiv on Sep 6th 2022

Danny Broere Lab Sterics
Broere Group

[36]   Sander D. de Vos, Maartje Otten, Tim Wissink, Daniël L. J. Broere, Emiel J. M. Hensen, Robertus, J. M. Klein Gebbink
Hydrogen Evolution Electrocatalysis with a Molecular Cobalt Bis(alkylimidazole)methane Complex in DMF: a Critical Activity Analysis
ChemSusChem 2022, e202201308

Broere Group

[35]   Daniël L. J. Broere
Synthetic molecular cluster hints at mechanism of nitrogen fixation
Nature 2022, 607, 37-38 

[34] Cody B. van Beek,# Lars Killian,# Martin Lutz, Markus Weingarth, Arun S. Asundi, Ritimukta Sarangi, Robertus J. M. Klein Gebbink,  Daniël L. J. Broere*
E-selective Semi-hydrogenation of Alkynes Under Mild Conditions  by a Diruthenium Hydride Complex
Chem. Eur. J. 2022, e202202527
# Equal contribution — First published on ChemRxiv on May 4th 2022

Broere Group

[33] Cody B. van Beek,# Lars Killian,# Martin Lutz, Daniël L. J. Broere*
Persistence of a Ru3(µ-CO)3(CO)5 cluster bound to a PNNP ‘expanded pincer’ ligand in different protonation states
Eur. J. Inorg. Chem. 2022, DOI: 10.1002/ejic.202200191 
#Equal contribution

Broere Group

[32]  Roel L. M Bienenmann, Alexandra J. Schanz, Pascalle L. Ooms, Martin Lutz, Daniël L. J. Broere*
A Well‐Defined Anionic Dicopper(I) Monohydride Complex that Reacts like a Cluster
Angew. Chem. Int. Ed. 2022 e202202318e202202318
First published on ChemRxiv on Feb 11th 2022

Broere Group

[31]  Cody B. van Beek, Nicolaas P. van Leest, Martin Lutz, Robertus J. M. Klein Gebbink, Bas de Bruin, Daniël L. J. Broere*
Combining Metal-Metal Cooperativity, Metal-Ligand Cooperativity and Chemical Non-Innocence in Diiron Carbonyl Complexes
Chem. Sci., 2022, 13, 2094-2104.
First published on ChemRxiv on September 30th 2021

Broere Group

[30]  Errikos Kounalis, Daniël L. J. Broere*
Redox-Active Ligands in Organometallic Chemistry
Invited book chapter for Comprehensive Organometallic Chemistry IV 2021

[29]  Arthur R. Scheerder, Martin Lutz, Daniël L. J. Broere*
Unexpected Reactivity of a PONNOP ‘Expanded Pincer’ Ligand
ChemComm 2020, 56, 8198-8201 
First published on ChemRxiv on March 25th 2020

Broere Group

[28]  Errikos Kounalis, Martin Lutz, Daniël L. J. Broere*
Tuning the Bonding of a μ-Mesityl Ligand on Dicopper(I) through a Proton-Responsive Expanded PNNP Pincer Ligand
Organometallics 2020, 39, 585-592 

Danny Broere
Broere Group

[27]  Errikos Kounalis, Martin Lutz, Daniël L. J. Broere*
Cooperative H2 Activation on Dicopper(I) Facilitated by Reversible Dearomatization of an ‘Expanded PNNP Pincer’ Ligand
Chem. Eur. J. 201925, 13280-13284
First published on ChemRxiv on December 4th 2019

Broere Lab ChemEurJ2019TOC
Broere Group

[26]  Broere, D.L.J.*
Transition metal-catalyzed dehydrogenation of amines
Phys. Sci. Rev. 2018,DOI: 10.1515/psr-2017-0029

[25] Broere, D.L.J.*; Holland, P. L.*
Boron Compounds Tackle Dinitrogen
Science2018359, 871

Previous Research (prior to Utrecht University):

[24] McWilliams, S.F.# Broere, D.L.J.#; Halliday, C.J.V., Bhutto, S., Mercado, B.Q.; Holland, P. L. # = equal contribution
Coupling dinitrogen and hydrocarbons through aryl migration
Nature 2020584, 221-226

[23] Broere, D.L.J.*; Mercado, B.Q.; Holland, P. L.
Selective Conversion of CO2 into Isocyanate by Low-Coordinate Iron Complexes
Angew. Chem. Int. Ed. 2018130, 6617-6621

[22] Broere, D.L.J.*; Mercado, B.Q.; Lukens, J.T.; Vilbert, A.C.; Banerjee, G.; Lant, H.M.C.; Lee, S.H.; Bill, E.; Sproules, S.; Lancaster, K.M.; Holland, P. L.
Reversible Ligand-Centered Reduction in Low-Coordinate Iron Formazanate Complexes
Chem. Eur. J. 201824, 9417-9425

[21] Broere, D.L.J.*; Mercado, B.Q.; Bill, E.; Lancaster, K.M.; Sproules, S.; Holland, P. L.
Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry
Inorg Chem. 201857, 9580–9591

[20] Wu, Y.; Jiang, J.; Weng, Z.; Wang, M.; Broere, D.L.J.; Zhong, Y.; Brudvig, G.W.; Feng, Z.; Wang, H.
Electroreduction of CO2 Catalyzed by a Heterogenized Zn-Porphyrin Complex with a Redox-Innocent Metal Center
ACS Cent. Sci. 20173, 847-852

[19] Broere, D.L.J.; Coric,I.; Brosnahan, A.; Holland, P.L.H.
Quantitation of THF content in Fe[N(SiMe3)2]2 • x THF
Inorg. Chem. 2017, 56, 3140-3143

[18] Kuijpers, P.F.; Tiekink, M.J.; Breukelaar, W.; Broere, D.L.J.; van Leest, N.P.; van der Vlugt, J.I.; Reek, J.N.H.; de Bruin, B.
Nitrene-radical approach to Saturated Heterocycles; Cobalt Porphyrin Catalysed Intramolecular Ring-Closing C-H Amination
of Aliphatic Azides
Chem. Eur. J. 2017, 23, 7945-7952

[16] Bagh, B.; Broere, D.L.J.; Sinha, V.; Kuijpers, P.F.; Demeshko, S.; Siegler, M.A.; de Bruin. B.; van der Vlugt. J.I.
Catalytic Synthesis of N-Heterocycles via Direct C(sp3)-H Amination using an Air-stable Fe(III) Species with a Redox-Active Ligand
J. Am. Chem. Soc. 2017139, 5117-5124

[15] Vreeken, V.; Broere, D.L.J.; Jans, A.C.H.; Lankelma, M.; Reek, J.N.H.; Siegler, M.A.; van der Vlugt, J.I.
Well-Defined Dinuclear Gold Complexes for Preorganization-Induced Selective Dual Gold Catalysis
Angew. Chem. Int. Ed. 201655, 10042-10046

[14] Bagh, B.; Broere, D.L.J.; Siegler, M.A.; van der Vlugt. J.I.
Redox-Active-Ligand Mediated Formation of an Acyclic Trinuclear Ruthenium Complex with Bridging Nitrido Ligands
Angew. Chem. Int. Ed. 2016, 55, 8381-8385

[13] Broere, D.L.J.; van Leest, N.P.; Siegler, M.A.; van der Vlugt, J.I.
Reversible Redox Chemistry and Catalytic C(sp3)-H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand
Inorg. Chem. 201655, 8603-8611

[12] Broere, D.L.J.; Plessius, R.; Tory, J.; Demeshko, S.; de Bruin, B.; Siegler, M. A.; Hartl, F.; van der Vlugt, J. I.
Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium
Chem. Eur. J. 201622, 13965-13975

[11] Broere, D.L.J.; Modder, D.K. ; Blokker, E. ; Siegler, M.A ; van der Vlugt, J.I.
Metal-Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands
Angew. Chem. Int. Ed. 2016, 55, 2406-2410

[10] Tazelaar, C.; van Dijk, T.; Nicolas, E. Broere, D.L.J.; Cardol,M.; Lutz, M.; Gudat, D.; Slootweg, J.C.; Lammertsma, K.
Tris(pyrazolyl)phosphines with Cu(I):From Monomers to Polymers
Dalton Trans. 201645, 2237-2249

[9] Pascui, A. E.; van Rees. K.; Zant, D. W.; Broere, D.L.J.; van der Vlugt, J.I.
Macrocyclic Platinum(II) complexes with a Bifunctional Diphosphine Ligand
Eur. J. Inorg. Chem. 2015, 5687-5693

[8] Broere, D.L.J.; Plessius, R.; van der Vlugt, J.I.
New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
Chem. Soc. Rev. 2015, 44, 6886-6915

[7] Broere, D.L.J.; Demeshko, S.; de Bruin, B.; Pidko, E. A.; Reek, J.N.H.; Siegler, M. A.; Lutz, M.; van der Vlugt, J. I.
Dinuclear Pd Complexes with Two Ligand-Centered Radicals and a Single Bridging Ligand: Tuning of Magnetic
Chem. Eur. J. 2015, 21, 5879-5886

[6] Drost, R. M.; Broere, D.L.J.; Hoogenboom, J.; de Baan, S.N.; Lutz, M.; de Bruin, B.; Elsevier, C.J.
Allyl-Pd(II) Histidylidene Complexes and Their Application in Z-Selective Transfer Semihydrogenation of Alkynes
Eur. J. Inorg. Chem. 20156, 982-996

 [5] Broere, D.L.J.; Metz, L.L.; de Bruin, B.; Reek, J.N.H.; Siegler, M. A.; van der Vlugt, J.I.
Redox-Active Ligand-Induced Homolytic Bond Activation
Angew. Chem. Int. Ed. 201554, 516-1520

[4] Broere, D.L.J.; de Bruin, B.; Reek, J.N.H.; Lutz, M.; Dechert, S.; van der Vlugt, J. I. Intramolecular Redox-Active Ligand-to-Substrate Single Electron Transfer: Radical Reactivity with Pd(II)
(Front cover, featured in JACS spotlights and C2W)
J. Am. Chem. Soc. 2014136, 11574-11577

[3] Den Heeten, R.; van der Boon, L.J.P.; Broere, D.L.J.; Janssen, E.; de Kanter, F.J.J.; Ruijter, E.; Orru, R.V.A.
Concise Synthesis of Highly Substituted Benzo[a]quinolizines by a Multicomponent Reaction/Allylation/Heck Sequence
Eur. J. Org. Chem. 2012, 275-280

[2] Tazelaar, C.G.J.; Lyaskovskyy, V.; van Dijk, T.; Broere, D.L.J.; Kolfschoten, L.A.; Osman Hassan Khiar, R.; Lutz, M.; Slootweg,
J.C.; Lammertsma, K.
Tris(pyrazolyl)phosphine Oxides. Synthesis and Coordination Chemistry with Cu(I)
Organometallics2012, 31, 3308-3315.

[1] Broere, D.L.J.; Ruijter, E.
Recent Advances in Transition-Metal-Catalyzed [2+2+2]-Cyclo(co)trimerization Reactions
Synthesis201244, 2639-2672